In 1935, Linus Pauling introduced the novel concept of backbonding to explain the shorter than expected Ni-C bonds observed in the electron diffraction structure of Ni(CO)4. Like many concepts in chemistry, backbonding is better illustrated than described:
In this simplified scheme above, CO gives electronic juice to the metal's empty and receptive d-orbital (left-hand side). At the same time, the metal gives back electrons to the CO (right-hand side) using a different full d-orbital: the two sketches overlap. They are synergistic.
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