Tuesday, January 26, 2010

Beryllium Is A Sweet Precious Gift


Different variations of beryl, including 1. golden beryl crystal, 2. heliodore. 3. emerald, 4. aquamarine, 5. morganite

The root word of beryllium is old and familiar and lurks beneath the surface of the commonly used word brilliant:

brilliant
1680s, from Fr. brilliant "sparkling, shining" prp. of briller "to shine" (16c.), from It. brillare "sparkle, whirl," perhaps from V.L. *berillare "to shine like a beryl," from berillus "beryl, precious stone," from L. beryllus (see beryl). In reference to diamonds (1680s) it means a flat-topped cut invented 17c. by Venetian cutter Vincenzo Peruzzi.

Beryl and emeralds were known to Pliny the Elder nearly 2000 years ago and he first observed a physical similarity between the two. In the Middle Ages, transparent, colorless beryl was used to make optical lenses, whence the German word Brille which today still means eyeglasses. The invention and manufacture of actual glass spectacles developed in Italy in the 13th century and improvements followed closely with the development of optics.

The minerologist R.-J. Haüy also observed the remarkable similarity between beryl and emerald (hardness and density), and he persuaded the pre-eminent chemist/pharmacist of his time (late 18th century) Louis Vauquelin (of Paris) to analyze the stones to see if they were chemically alike. In 1798, Vauquelin showed that both minerals contained not only alumina and silica as had previously been known, but also a new element, beryllium, which he extracted as the oxide from emerald. Fredrich Wöhler first prepared metallic beryllium by reducing BeCl2, with potassium metal. Thus the new element beryllium was discovered.

One caveat: until around 1948, beryllium (symbol = Be) was also known as Glucinium (symbol Gl), reportedly because of the sweetish taste of its chloride salts.

WARNING: Beryllium is considered to be highly toxic so do not, repeat do not taste or chew your precious emeralds!

6 comments:

  1. I didn't know all of this about beryllium. More importantly, I didn't know I wanted to know about beryllium. Turns out I did. Great post!

    ReplyDelete
  2. Hey Pete, thanks!
    Beryllium is an odd and weird element. It's used in a lot of high tech applications too. It has a bit of an overblown reputation for toxicity IMO, and it's really the dust that is bad for you. And like chrome out of a bumper, I don't think it's possible to suck the berrylium out of an emerald.
    My goal with this series of chemistry posts is to make even the most boring sh_t seem interesting. Fittingly, boron is up next! Glad you enjoyed.

    ReplyDelete
  3. Your blog never fails to be entertaining, whether about minerals, gems, your family or any other topic. Thanks for posting.

    ReplyDelete
  4. I like aquamarines (uncooked).

    Me too (it's my birthstone).

    ReplyDelete
  5. I had some cherrystone clams if that counts.

    ReplyDelete