Fertilizer bombs typically use ammonium nitrate, NH
4NO
3. Bombers use it because the stuff is so ubiquitous and so plentiful.
Wiki draws a pretty picture of ammonium nitrate, which partially reveals its explosive potential:
Don't skip over that structure--it's a work of art: two very different nitrogen atoms separate elements of hydrogen and oxygen. On the left, four hydrogens surround a central nitrogen while on the right, three oxygen atoms surround a central nitrogen. There's an unbalanced symmetry. Those H's and O's would love to get together and quench, making water, leaving the naked nitrogens to couple, making N
2 which is essentially air. The chemical structure of ammonium nitrate is a depiction of air separating water.
We never hear about spontaneous explosions of ammonium nitrate. Why is that? An old word from the Greek called
stoichiometry answers why. Try and balance the chemical equation of NH
4NO
3 making N
2 and H
2O:
NH
4NO
3 => N
2 + H
2O
Look easy? I gave up. The reason is that the hydrogen to oxygen ratio is inherently 4 to 3 on one side and 2 to 1 on the other. No amount of tweaking the coefficients will balance that reaction. The stoichiometry just doesn't work.
This brings up just how fertilizer bombs do work, because they do make air and water from ammonium nitrate. There is always a little admixture of carbon (typically fuel oil) but charcoal would work too. The carbon combines with the "excess" oxygen present in NH
4NO
3, making CO
2. This trick even has a name:
cf. detonation
vs. deflagration
Here's a question for any munitions experts out there: were ANFO's involved in Boston? I've heard that the differing sounds of detonation versus deflagration are diagnostic.
A second question is technical: is it possible (in theory) to isotopically label the nitrogen in manufactured ammonium nitrate and thus, after isotopic analysis of air samples at the bombing site prior to mixing, identify the source?
____________
[Added] Well
this breaking news should cause a spike in ammo and food prices. The report says that water sprayed on NH
4NO
3 made it explode. That may actually have been heat from the fire or could have resulted from of what's called heat of hydration when a dry salt suddenly mixes with water. Some salts suddenly mixed with water actually make the water colder.
Ammonium nitrate (AN) is not known to chemically react with water in an explosive way. However, if heated it reacts explosively:
2NH
4NO
3 => 2N
2 + O
2 + 4H
2O
Now that reaction
really produces a sky-full: nitrogen, oxygen, & cloud.